HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Cyanopyridine → HCID 9834654, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Cyanopyridine | HCID 79 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Benzoic acid, 2-mercapto-, methyl ester | HCID 21009 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 9834654 | HCID 9834654 | 43.4% |
Reaction Steps
Methyl thiosalicylate (1.8 g, 10.7 mM) and 3-cyanopyridine (1.1 g, 10.56 mM) were dissolved in toluene (5 ml), and then triethylamine (2 ml, 14.4 mM) was added thereto. After heating the mixture under reflux for 48 hours, the same processes as described in Reference Example 1 were performed to give the title compound as crystals (1.1 g, 43.4%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06794383B2 |
| Source dataset | uspto-grants-2004_09 |
| ORD ID | ord-d3c8752b4f3a40a79840510b13262de2 |
| Source note | uspto-grants-2004_09 |