4-Methoxy-2-nitroaniline → HCID 4059671, compound

HRID 1007182Notes

Reaction equation

HRID 1007182 reaction equation
[Cl:1][C:2]1[N:10]=[CH:9][CH:8]=[CH:7][C:3]=1[C:4](Cl)=[O:5].[CH3:11][O:12][C:13]1[CH:19]=[CH:18][C:16]([NH2:17])=[C:15]([N+:20]([O-:22])=[O:21])[CH:14]=1>>[Cl:1][C:2]1[C:3]([C:4]([NH:17][C:16]2[CH:18]=[CH:19][C:13]([O:12][CH3:11])=[CH:14][C:15]=2[N+:20]([O-:22])=[O:21])=[O:5])=[CH:7][CH:8]=[CH:9][N:10]=1

Participants

3

Reactant 2

HCID 667934-Methoxy-2-nitroanilineHCID 27745412-Chloronicotinoyl chloride

Product 1

HCID 4059671HCID 4059671, compound

Procedure

The title compound was prepared from 2-chloronicotinoyl chloride and 4-methoxy-2-nitroaniline and was obtained as a yellow solid as described in Example 1. 1H NMR (CDCl3): 10.76 (s, 1H), 8.78 (d, J=9.3, 1H), 8.58-8.55 (m, 1H), 8.13-8.09 (m, 1H), 7.73 (d, J=3.0, 1H), 7.45-7.40 (m, 1H), 7.34-7.28 (m, 1H0, 3.90 (s, 3H).

Workup

  1. customwas obtained as a yellow solid

Sources & evidence

ORD record
ord-06547aa9f0c04a7ca1a9c2df60f0352e
Source dataset
uspto-grants-2004_09
Patent number
US06794397B2

Reaction notes

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