4-Amino-3-nitrobenzonitrile → HCID 9966182, compound

HRID 1007196Notes

Reaction equation

HRID 1007196 reaction equation
[Cl:1][C:2]1[CH:10]=[CH:9][C:5]([C:6](Cl)=[O:7])=[CH:4][N:3]=1.[NH2:11][C:12]1[CH:19]=[CH:18][C:15]([C:16]#[N:17])=[CH:14][C:13]=1[N+:20]([O-:22])=[O:21]>>[Cl:1][C:2]1[N:3]=[CH:4][C:5]([C:6]([NH:11][C:12]2[CH:19]=[CH:18][C:15]([C:16]#[N:17])=[CH:14][C:13]=2[N+:20]([O-:22])=[O:21])=[O:7])=[CH:9][CH:10]=1

Participants

3

Reactant 2

HCID 5959014-Amino-3-nitrobenzonitrileHCID 27821656-Chloronicotinoyl Chloride

Product 1

HCID 9966182HCID 9966182, compound

Procedure

The title compound was prepared from 6-chloronicotinoyl chloride and 4-amino-3-nitrobenzonitrile and was obtained as a light yellow solid as described in Example 1. 1H NMR (CDCl3): 11.58 (s, 1H), 9.18 (d, J=8.7, 1H), 9.04 (d, J=2.4, 1H), 8.65 (d, J=2.1, 1H), 8.26-8.22 (m, 1H), 8.00-7.96 (m, 1H), 7.56 (d, J=9.0, 1H).

Workup

  1. customwas obtained as a light yellow solid

Sources & evidence

ORD record
ord-b41da0fb8039467bb1fef198b257404c
Source dataset
uspto-grants-2004_09
Patent number
US06794397B2

Reaction notes

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