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HRID1009831

反应详情

EQUATION

反应方程式

HRID 1009831 的结构方程式

REACTANTS

反应物

1
反应SMILES：C=C(C)[C@H]1C[C@@H](C(=O)OCC)N(C(=O)OC(C)(C)C)[C@H]1c1ccc(OC)c(OCCCOC)c1
HCID16124546

未命名化合物

PRODUCTS

产物

1
反应SMILES：CCOC(=O)[C@@H]1C[C@@H](C(C)C)[C@H](c2ccc(OC)c(OCCCOC)c2)N1C(=O)OC(C)(C)C
HCID16124547

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
反应SMILES：[Pd]
催化剂HCID23938

Palladium

Pd

反应SMILES：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

A solution of (2S,4R,5R)-4-Isopropenyl-5-[4-methoxy-3-(3-methoxy-propoxy)-phenyl]-pyrrolidine-1,2-dicarboxylic acid 1-tert-butyl ester 2-ethyl ester VIIa (0.3 g) in 10 mL of toluene is treated with 50 mg of 5% palladium on carbon. The suspension is stirred under an atmosphere of hydrogen for 2 hours at room temperature and filtered. The solvent is removed in vacuum to give the desired compound as an oil.

WORKUP

后处理

  1. filtrationfiltered
  2. customThe solvent is removed in vacuum