HuagongsheHuagongshe Chemistry Print Report · For research reference only
Azobisisobutyronitrile → HCID 86619237, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | Maleic Anhydride | HCID 7923 | — |
| Reactant | Propylene glycol methyl ether acetate | HCID 7946 | — |
| Reactant | tert-Butyl acrylate | HCID 15458 | — |
| Reactant | 2-Hydroxyethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate | HCID 12033823 | — |
| Reactant | Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 1,1-dimethylethyl ester | HCID 15607334 | — |
| Product | HCID 86619237 | HCID 86619237 | 48% |
Reaction Steps
T-butyl acrylate (30 g), maleic anhydride (10 g), t-butyl 5-norbornene-2-carboxylate (12.05 g) and 2-hydroxyethyl 5-norbornene-2-carboxylate (7.47 g) were mixed with azobisisobutyronitrile (AIBN) (1.2 g) as a polymerization initiator and propyleneglycol methyl ether acetate (PGMEA) (157 g) as a polymerization solvent. The resulting mixture was reacted at approximately 67° C. for approximately 12 hours, and precipitated in normal hexane and dehydrated to obtain an organic polymer compound with yield of approximately 48% (see FIG. 2).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07977035B2 |
| Source dataset | uspto-grants-2011_07 |
| ORD ID | ord-611bfc5fb9404afaa64ed355008a2df6 |
| Source note | uspto-grants-2011_07 |