HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 23117157, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Boron tribromide | HCID 25134 | — |
| Reactant | HCID 67219348 | HCID 67219348 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 23117157 | HCID 23117157 | 30% |
Reaction Steps
Boron tribromide 1M in CH2Cl2 was added to a solution of 1-adamantyl-(2-chloro-4,6-dimethoxyphenyl)methanone (7 g, 21.0 mmoles) and CH2Cl2 (30 ml). The mixture was warmed overnight and then poured into water, extracted with ethyl acetate, dried over Na2SO4 and concentrated under vacuum to give the expected product (1.9 g, 30%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07977364B2 |
| Source dataset | uspto-grants-2011_07 |
| ORD ID | ord-61947a13f59f46318d42b690fbe326e7 |
| Source note | uspto-grants-2011_07 |