1-Bromohexane → 1-Ethynyl-2-(2-(S)-methylbutyl)naphthalene

HRID 1011847Notes

Reaction equation

C(C1[C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)C=CC=1CCCCCC)#C.Br[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25].Br[CH2:27][C@@H:28]([CH3:31])[CH2:29][CH3:30]>>[C:21]([C:22]1[C:7]2[C:12](=[CH:11][CH:10]=[CH:9][CH:8]=2)[CH:25]=[CH:24][C:23]=1[CH2:27][C@@H:28]([CH3:31])[CH2:29][CH3:30])#[CH:20]

Participants

Reactant 3

HCID 81011-Bromohexane

HCID 54641671-Bromo-2-methylbutane, (+)-

HCID 21954826HCID 21954826, compound

Product 1

HCID 866349771-Ethynyl-2-(2-(S)-methylbutyl)naphthalene

Procedure

1-Ethynyl-2-(2-(S)-methylbutyl)naphthalene was prepared in a similar manner to 1-ethynyl-2-hexylnaphthalene, except that bromohexane was replaced by 1-bromo-2-(S)-methylbutane.

Sources & evidence

ORD record: ord-f134996ec3b14bc18dc743099acf7540
Source dataset: uspto-grants-2011_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07977441B2

Reaction notes

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