HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl 2-acetylacetoacetate → ethyl 1-(3,4-dichlorophenyl)-3,5-dimethyl-1H-pyrazole-4-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl 2-acetylacetoacetate | HCID 79063 | — |
| Reactant | (3,4-Dichlorophenyl)hydrazine monohydrochloride | HCID 3084323 | — |
| Product | ethyl 1-(3,4-dichlorophenyl)-3,5-dimethyl-1H-pyrazole-4-carboxylate | HCID 1491356 | 32% |
Reaction Steps
In analogy to the procedure described in Example 38A], 3,4-dichlorophenylhydrazine hydrochloride and ethyl diacetoacetate gave the title compound in 32% yield as yellow solid. MS: 313.0 (MH+, 2 Cl).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07977358B2 |
| Source dataset | uspto-grants-2011_07 |
| ORD ID | ord-bcce143b3a964ad4810b96635a7bb0c1 |
| Source note | uspto-grants-2011_07 |