Methyl iodide → Perchlorate

Participants

Reaction Steps

Furthermore, the 3-(1-naphthyl)quinoline (2-2) (70 mg, 0.27 mmol) was dissolved in 10 ml of acetone, and further methyl iodide (130 μl, 2 mmol) was added thereto, which then was stirred for 10 hours. The solvent was removed therefrom and 20 mL of methanol was then added thereto. Subsequently, sodium perchlorate (0.12 g, 1.0 mmol) was added thereto and thereby salt exchange (ion exchange) was performed. Thus, perchlorate of 3-(1-naphthyl)quinolinium ion (quinolinium ion derivative 2) was obtained. The yield amount of the quinolinium ion derivative 2 perchlorate thus obtained was 93 mg and the yield from the 3-(1-naphthyl)quinoline (2-2) was 93%. The instrumental analysis data of this quinolinium ion derivative 2 perchlorate is indicated below.

Provenance & Evidence