Water → HCID 12290225, compound

HRID 1016562Notes

Reaction equation

HRID 1016562 reaction equation
[C:1]([C:3]([C:8]1[CH:13]=[CH:12][C:11]([Cl:14])=[C:10]([Cl:15])[CH:9]=1)=[CH:4][C:5]([O-:7])=[O:6])#N.[K+].S(=O)(=O)(O)[OH:18].O>C(O)=O>[Cl:15][C:10]1[CH:9]=[C:8]([C:3]2[C:1](=[O:18])[O:6][C:5](=[O:7])[CH:4]=2)[CH:13]=[CH:12][C:11]=1[Cl:14]

Participants

5

Reactant 3

HCID 962WaterHCID 1118Sulfuric AcidHCID 70135999HCID 70135999, compound

Product 1

HCID 12290225HCID 12290225, compound

Reagents, catalysts & solvents 1

HCID 284Formic AcidSolvent

Procedure

25.8 g (92 mmol) of potassium 3-cyano-3-(3,4-dichlorophenyl)acrylate were dissolved in 200 ml of 88% strength formic acid and admixed dropwise with 15 ml of concentrated sulfuric acid. The mixed was then heated under reflux for 3 h, poured at 90° C. into 2.5 l of water and stirred for 1 h, and the product was filtered off, washed with water and dried. Yield: 18.9 g, m.p. 112° C.

Workup

  1. temperatureThe mixed was then heated
  2. temperatureunder reflux for 3 h
  3. filtrationthe product was filtered off
  4. washwashed with water
  5. customdried

Sources & evidence

ORD record
ord-b3943ad0192442b0a5b22875bd46a832
Source dataset
uspto-grants-2002_11
Patent number
US06476061B1

Reaction notes

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