HCID 12073826, compound → HCID 15512998, compound

HRID 1019242Notes

Reaction equation

HRID 1019242 reaction equation
[CH3:1][C@:2]12[CH2:12][CH2:11][C@@H:10]3[CH2:13][C@:7]1([O:8][C:9]3([CH3:15])[CH3:14])[CH:6]=[CH:5][CH2:4][CH2:3]2>C(Cl)(Cl)Cl>[CH3:1][C@:2]12[CH2:12][CH2:11][C@@H:10]3[CH2:13][C@:7]1([O:8][C:9]3([CH3:15])[CH3:14])[C:6]([CH2:5][CH2:6][CH2:7][OH:8])=[CH:5][CH2:4][CH2:3]2

Participants

3

Reactant 1

HCID 12073826HCID 12073826, compound

Product 1

HCID 15512998HCID 15512998, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Oil, [α]D10+24.6°, (c=0.62, chloroform) MS: 264 (M+, 85), 249 (7), 246 (15), 231 (8), 41 (100). 1H NMR (CDCl3, δ): 0.89 (s, 3 H, 6-CH3), 1.23 (s, 3 H, 10-CH3), 1.34 (s, 3 H, 10-CH3), 3.64 (t, J=7.0 Hz, 2 H, 3′-H/2R), 5.70 (t, J=3.6 Hz, 1 H, 3-H).

Sources & evidence

ORD record
ord-938bbeea94cf47df894e0f2d0180e113
Source dataset
uspto-grants-2002_11
Patent number
US06486201B1

Reaction notes

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