Chloroform → HCID 9837385, compound

HRID 1019245Notes

Reaction equation

HRID 1019245 reaction equation
[CH3:1][C:2]12[CH2:11][CH2:10][C@@H:9]([C:12]([OH:15])([CH3:14])[CH3:13])[CH2:8][C:7]1=[CH:6][C:5](=O)[CH2:4][CH2:3]2.[CH:17](Cl)(Cl)Cl>>[CH3:17][C:5]1[CH2:4][CH2:3][C@@:2]2([CH3:1])[CH2:11][CH2:10][C@@H:9]3[CH2:8][C@:7]2([O:15][C:12]3([CH3:14])[CH3:13])[CH:6]=1

Participants

3

Reactant 2

HCID 6212ChloroformHCID 131723657HCID 131723657, compound

Product 1

HCID 9837385HCID 9837385, compound

Procedure

White solid,: mp 38-39° C., [α]D1045.8° (c=0.47, chloroform). MS: 220 (M+, 15), 205 (50), 187 (14), 162 (31), 147 (50), 31 (100); 1H NMR (CDCl3, δ): 0.90 (s, 3 H, 6-CH3), 1.21 (s, 3 H, 10-CH3), 1.33 (s, 3 H, 10-CH3), 1.37 (s, 3 H, 3-CH3), 5.16 (s, 1 H, 2-H).

Sources & evidence

ORD record
ord-4939ba67a9024f749c6033b75b5e1862
Source dataset
uspto-grants-2002_11
Patent number
US06486201B1

Reaction notes

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