Imidazole → imidazole LiTFSI

HRID 1019461Notes

Reaction equation

HRID 1019461 reaction equation
[NH:1]1[CH:5]=[CH:4][N:3]=[CH:2]1.[Li+:6].[C:7]([S:11]([N-:14][S:15]([C:18]([F:21])([F:20])[F:19])(=[O:17])=[O:16])(=[O:13])=[O:12])([F:10])([F:9])[F:8]>>[NH:1]1[CH:5]=[CH:4][N:3]=[CH:2]1.[Li+:6].[C:18]([S:15]([N-:14][S:11]([C:7]([F:10])([F:9])[F:8])(=[O:13])=[O:12])(=[O:16])=[O:17])([F:20])([F:19])[F:21]

Participants

3

Reactant 2

HCID 795ImidazoleHCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanide

Product 1

HCID 131731358imidazole LiTFSIYield 137.4%

Conditions

Temperature
40 °C

Procedure

14.2 g of purified imidazole and 20 g of LiTFSI were put into a round bottom flask and slowly stirred for 2 hours under a nitrogen circumstance of 40° C., thereby obtaining 34 g of imidazole-LiTFSI eutectic mixture.

Sources & evidence

ORD record
ord-c7c21d9897bb41fca3c57edbb966395d
Source dataset
uspto-grants-2014_05
Patent number
US08715866B2

Reaction notes

Loading…