1H-1,2,4-Triazole → 1,2,4-Triazole LiTFSI

HRID 1019462Notes

Reaction equation

HRID 1019462 reaction equation
[NH:1]1[CH:5]=[N:4][CH:3]=[N:2]1.[Li+:6].[C:7]([S:11]([N-:14][S:15]([C:18]([F:21])([F:20])[F:19])(=[O:17])=[O:16])(=[O:13])=[O:12])([F:10])([F:9])[F:8]>>[NH:1]1[CH:5]=[N:4][CH:3]=[N:2]1.[Li+:6].[C:18]([S:15]([N-:14][S:11]([C:7]([F:10])([F:9])[F:8])(=[O:13])=[O:12])(=[O:16])=[O:17])([F:20])([F:19])[F:21]

Participants

3

Reactant 2

HCID 92571H-1,2,4-TriazoleHCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanide

Product 1

HCID 1317313591,2,4-Triazole LiTFSIYield 137%

Conditions

Temperature
70 °C

Procedure

3.6 g of purified 1,2,4-triazole and 5 g of LiTFSI were put into a round bottom flask and slowly stirred for 4 hours under a nitrogen circumstance of 70° C., thereby obtaining 8.5 g of targeted eutectic mixture.

Sources & evidence

ORD record
ord-eaa34ca9562e4e5fb277211aaab5e690
Source dataset
uspto-grants-2014_05
Patent number
US08715866B2

Reaction notes

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