Imidazole → imidazole LiBETI

HRID 1019465Notes

Reaction equation

HRID 1019465 reaction equation
[NH:1]1[CH:5]=[CH:4][N:3]=[CH:2]1.[Li+:6].[C:7]([F:27])([F:26])([F:25])[C:8]([S:11]([N-:14][S:15]([C:18]([F:24])([F:23])[C:19]([F:22])([F:21])[F:20])(=[O:17])=[O:16])(=[O:13])=[O:12])([F:10])[F:9]>>[NH:1]1[CH:5]=[CH:4][N:3]=[CH:2]1.[Li+:6].[C:19]([F:22])([F:21])([F:20])[C:18]([S:15]([N-:14][S:11]([C:8]([F:10])([F:9])[C:7]([F:25])([F:26])[F:27])(=[O:12])=[O:13])(=[O:16])=[O:17])([F:24])[F:23]

Participants

3

Reactant 2

HCID 795ImidazoleHCID 12096715Lithium bis[(pentafluoroethyl)sulfonyl]azanide

Product 1

HCID 131731362imidazole LiBETIYield 129.3%

Conditions

Temperature
50 °C

Procedure

5.3 g of purified imidazole and 10 g of LiBETI were put into a round bottom flask and slowly stirred for 50 minutes under a nitrogen circumstance of 50° C., thereby obtaining 15.2 g of imidazole-LiBETI eutectic mixture.

Sources & evidence

ORD record
ord-c96c84f9deb24b0c8262da476c9f6170
Source dataset
uspto-grants-2014_05
Patent number
US08715866B2

Reaction notes

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