Pyrimidine → HCID 131731363, compound

HRID 1019466Notes

Reaction equation

[N:1]1[CH:6]=[CH:5][CH:4]=[N:3][CH:2]=1.[Li+:7].[C:8]([S:12]([N-:15][S:16]([C:19]([F:22])([F:21])[F:20])(=[O:18])=[O:17])(=[O:14])=[O:13])([F:11])([F:10])[F:9]>>[N:1]1[CH:6]=[CH:5][CH:4]=[N:3][CH:2]=1.[Li+:7].[C:19]([S:16]([N-:15][S:12]([C:8]([F:11])([F:10])[F:9])(=[O:14])=[O:13])(=[O:17])=[O:18])([F:21])([F:20])[F:22]

Participants

Reactant 2

HCID 9260Pyrimidine

HCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanide

Product 1

HCID 131731363HCID 131731363, compoundYield 140.8%

Conditions

Temperature: 40 °C

Procedure

10 g of purified pyrimidine and 11.94 g of LiTFSI were put into a round bottom flask and slowly stirred for 1 hour under a nitrogen circumstance of 40° C., thereby obtaining 21.5 g of pyrimidine-LiTFSI eutectic mixture.

Sources & evidence

ORD record: ord-a3b55992030d4bda86d4712a30e702de
Source dataset: uspto-grants-2014_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08715866B2

Reaction notes

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