2-Ethoxypyridine → 2-ethoxypyridine LiTFSI

HRID 1019467Notes

Reaction equation

HRID 1019467 reaction equation
[CH2:1]([O:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][N:5]=1)[CH3:2].[Li+:10].[C:11]([S:15]([N-:18][S:19]([C:22]([F:25])([F:24])[F:23])(=[O:21])=[O:20])(=[O:17])=[O:16])([F:14])([F:13])[F:12]>>[CH2:1]([O:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][N:5]=1)[CH3:2].[Li+:10].[C:22]([S:19]([N-:18][S:15]([C:11]([F:14])([F:13])[F:12])(=[O:17])=[O:16])(=[O:20])=[O:21])([F:24])([F:23])[F:25]

Participants

3

Reactant 2

HCID 844992-EthoxypyridineHCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanide

Product 1

HCID 1317313642-ethoxypyridine LiTFSIYield 157.6%

Conditions

Temperature
50 °C

Procedure

10 g of purified 2-ethoxypyridine and 7.77 g of LiTFSI were put into a round bottom flask and slowly stirred for 50 minutes under a nitrogen circumstance of 50° C., thereby obtaining 17.5 g of 2-ethoxypyridine-LiTFSI eutectic mixture.

Sources & evidence

ORD record
ord-7100b316dfe849aabf5c42c6b16eff45
Source dataset
uspto-grants-2014_05
Patent number
US08715866B2

Reaction notes

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