Acetamide → HCID 131731365, compound

HRID 1019468Notes

Reaction equation

HRID 1019468 reaction equation
[C:1]([NH2:4])(=[O:3])[CH3:2].[Li+:5].[C:6]([S:10]([N-:13][S:14]([C:17]([F:20])([F:19])[F:18])(=[O:16])=[O:15])(=[O:12])=[O:11])([F:9])([F:8])[F:7]>>[C:1]([NH2:4])(=[O:3])[CH3:2].[Li+:5].[C:17]([S:14]([N-:13][S:10]([C:6]([F:9])([F:8])[F:7])(=[O:12])=[O:11])(=[O:15])=[O:16])([F:19])([F:18])[F:20]

Participants

3

Reactant 2

HCID 178AcetamideHCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanide

Product 1

HCID 131731365HCID 131731365, compoundYield 152%

Procedure

5 g of purified acetamide and 6 g of LiTFSI were put into a round bottom flask and slowly stirred for 12 hours at a normal temperature under a nitrogen circumstance, and then moisture was removed therefrom in a vacuum oven for 3 days, thereby obtaining 11 g of acetamide-LiTFSI eutectic mixture.

Workup

  1. custommoisture was removed
  2. waitin a vacuum oven for 3 days

Sources & evidence

ORD record
ord-eb992f7f0bdc4e959670fa4f5762e7f8
Source dataset
uspto-grants-2014_05
Patent number
US08715866B2

Reaction notes

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