Alpha-Methylstyrene → HCID 86656477, compound

HRID 1024140Notes

Reaction equation

HRID 1024140 reaction equation
[CH3:1][C:2]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)=[CH2:3].[C:10]([C:14]1[CH:22]=[CH:21][C:17]([C:18]([CH3:20])=[CH2:19])=[CH:16][CH:15]=1)([CH3:13])([CH3:12])[CH3:11]>>[CH3:3][C:2]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)=[CH2:1].[C:10]([C:14]1[CH:15]=[CH:16][C:17]([C:18]([CH3:20])=[CH2:19])=[CH:21][CH:22]=1)([CH3:13])([CH3:11])[CH3:12]

Participants

3

Reactant 2

HCID 7407Alpha-MethylstyreneHCID 15354263HCID 15354263, compound

Product 1

HCID 86656477HCID 86656477, compound

Conditions

Temperature
-7.5 °C

Procedure

A resin G-2b is prepared in a manner similar to that of preparing the resin C-2b, except that 36.0 g of α-methylstyrene and 84.0 g of 4-tert-butyl-α-methylstyrene are used and that the polymerization reaction is allowed to proceed in a state where the temperature of the reaction mixed solution is maintained in the range of −8 to −7° C. in the former. The resin G-2b thus obtained (an α-methylstyrene/4-tert-butyl-α-methylstyrene homopolymer) has yield: 80 g, softening point: 212° C., number-average molecular weight (Mn): 2784, and weight-average molecular weight (Mw): 10024.

Workup

  1. customA resin G-2b is prepared in a manner similar to that
  2. customof preparing the resin C-2b
  3. additionmixed solution

Sources & evidence

ORD record
ord-f23d35a14aca464f9ec5e85a01090ef2
Source dataset
uspto-grants-2014_05
Patent number
US08722806B2

Reaction notes

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