Sodium Hydroxide → Nickel(2+) oleate

HRID 1025243Notes

Reaction equation

HRID 1025243 reaction equation
Cl[Ni:2]Cl.[C:4]([OH:23])(=[O:22])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11]/[CH:12]=[CH:13]\[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21].[OH-].[Na+]>CO>[C:4]([O-:23])(=[O:22])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11]/[CH:12]=[CH:13]\[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21].[Ni+2:2].[C:4]([O-:23])(=[O:22])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11]/[CH:12]=[CH:13]\[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]

Participants

5

Reactant 3

HCID 14798Sodium Hydroxide2×HCID 24385Nickel DichlorideHCID 445639Oleic Acid

Product 1

HCID 44146226Nickel(2+) oleate

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

1.30 g of NiCl2 was dissolved in 100 mL of methanol, and then 5.5 mL oleic acid was added. A NaOH solution with 0.8 g of NaOH in 200 mL of methanol was dropped into the solution under magnetic stirring conditions. The reaction was carried out for one hour. The observed green precipitate of Ni (II) oleate was extracted with hexane. The solvents were removed under vacuum overnight.

Workup

  1. extractionThe observed green precipitate of Ni (II) oleate was extracted with hexane
  2. customThe solvents were removed under vacuum overnight

Sources & evidence

ORD record
ord-17b4c63fe5e1458eb2ea2feda1496b1c
Source dataset
uspto-grants-2014_05
Patent number
US08728361B2

Reaction notes

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