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HRID1028260

反应详情

EQUATION

反应方程式

HRID 1028260 的结构方程式

REACTANTS

反应物

2
结构：CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-].[Ti+4]
HCID21801

Titanium(IV) n-butoxide

C16H36O4Ti

结构：CCP(=O)(O)CC(C)C(=O)O
HCID46216500

未命名化合物

PRODUCTS

生成物

1
结构：CCP(=O)(O)CC(C)C(=O)[O-].CCP(=O)(O)CC(C)C(=O)[O-].CCP(=O)(O)CC(C)C(=O)[O-].CCP(=O)(O)CC(C)C(=O)[O-].[Ti+4]
HCID131731421

未命名化合物

收率 96.3%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

180 g (1 mol) of 3-(ethylhydroxyphosphinyl)-2-methylpropionic acid (produced as in Example 17) and 170 g of titanium tetrabutoxide are refluxed in 500 ml of toluene for 40 hours. The resulting butanol is distilled off from time to time with proportions of toluene. The solution formed is subsequently freed of solvent to leave 184 g (91% of theory) of 3-(ethylhydroxyphosphinyl)-2-methylpropionic acid titanium salt.

WORKUP

后处理

  1. distillationThe resulting butanol is distilled off from time to time with proportions of toluene
  2. customThe solution formed