o-Iodonitrobenzene → HCID 24821366, compound

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Reaction Steps

The title compound was prepared with the analogous procedure described in example 1 using 1-Iodo-2-nitrobenzene (125 mg, 0.5 mmol) and nicotinanilide (119 mg, 0.6 mmol) as starting materials to yield the title compound as brown solid (91 mg, 67%). mp 110-112° C. 1H NMR (DMSO) δ 7.26 (d, J=7.3 Hz, 1 H), 7.32-7.63 (m, 8 H), 7.86 (d, J=7.6 Hz, 1 H), 7.89 (d, J=7.8 Hz, 1 H), 8.62 (d, J=3.0 Hz, 1 H), 8.72 (br s, 1 H); 13C NMR δ 111.0, 118.7, 123.8, 124.0, 124.4, 125.4, 127.6, 129.5, 130.2, 135.2, 136.4, 137.7, 140.3, 148.6, 149.6, 158.3. HRMS (FAB): cal. for C18H14N3 [M+H+]: 272.1188; found: 272.1180.

Provenance & Evidence