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HRID1028437

反应详情

EQUATION

反应方程式

HRID 1028437 的结构方程式

REACTANTS

反应物

2
结构：C[S-].[Na+]
HCID4378561

Sodium thiomethoxide

CH3NaS

结构：COc1c(COS(C)(=O)=O)cc(C(C)(C)C)cc1[N+](=O)[O-]
HCID58493954

未命名化合物

PRODUCTS

生成物

1
结构：COc1c(CSC)cc(C(C)(C)C)cc1[N+](=O)[O-]
HCID58493925

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：C1COCCO1
溶剂HCID31275

1,4-Dioxane

C4H8O2

CONDITIONS

反应条件

温度
40 °C

PROCEDURE

实验过程

At ambient temperature 1.50 g sodium thiomethoxide are added to a solution of 4.64 g 5-tert-butyl-2-methoxy-3-nitro-benzyl methanesulphonate in 50 ml of 1,4-dioxane. The solution is stirred overnight at 40° C. Then the solvent is removed and the residue is chromatographed on silica gel with cyclohexane/ethyl acetate (98:2→60:40) as eluant.

WORKUP

后处理

  1. customThen the solvent is removed
  2. customthe residue is chromatographed on silica gel with cyclohexane/ethyl acetate (98:2→60:40) as eluant