HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1028477Generated: October 30, 2026
1,3-Dibromo-5,5-dimethylhydantoin → Diethyl dioxobutanedioate
https://huagongshe.com/reaction/1028477
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 1,3-Dibromo-5,5-dimethylhydantoin | HCID 6479 | — |
| Reactant | 2,2'-Azobis(2,4-dimethyl-4-methoxyvaleronitrile) | HCID 85867 | — |
| Reactant | Diethyl tartrate | HCID 6993580 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | Diethyl dioxobutanedioate | HCID 263091 | — |
Reaction Steps
L-Tartaric acid diethyl ester (2.0 g), acetic acid (20 ml), 1,3-dibromo-5,5-dimethylhydantoin (6.0 g) and 2,2′-azobis(4-methoxy-2,4-dimethylvaleronitrile) (30 mg) were mixed, and the reaction solution was stirred at 55° C. for 3 hours. The reaction solution was concentrated under reduced pressure until its volume became 10 ml to afford a solution of diethyl dioxobutanedioate in acetic acid as a yellow liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US08735598B2 |
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| Source dataset | uspto-grants-2014_05 |
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| ORD ID | ord-4e47402c053a4f6dbc51fba8896a19f6 |
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| Source note | uspto-grants-2014_05 |
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