Triacetoxyperiodinane → HCID 19995529, compound

Participants

Reaction Steps

Under argon to a solution of (±)-(1R,2R,3R)-3-tert-butoxycarbonylamino -1,2,3,4-tetrahydro-1-isopropyloxy-2-naphthalenol (50 mg) in anhydrous methylene chloride (4 ml) was added Dess-Martin periodinane (100 mg). Agitation was maintained at room temperature for 2 hours. The reaction mixture was filtered on a silica gel column (10 g, elution ethyl acetate:cyclohexane, 1:9) to afford the title compound as an oil (38 mg).

Provenance & Evidence