huagongshe.com
HRID1030773

反应详情

EQUATION

反应方程式

HRID 1030773 的结构方程式

REACTANTS

反应物

3
结构：CC(=O)OC[C@H]1O[C@@H](n2cnc3c(N)ncnc32)[C@H](OC(C)=O)[C@H]1Br
HCID10982560

未命名化合物

结构：CC(=O)OC[C@H]1O[C@@H](n2cnc3c(=O)[nH]cnc32)[C@H](OC(C)=O)[C@H]1Br
HCID135465663

未命名化合物

结构：CC(=O)OC[C@H]1O[C@@H](n2cnc3c(=O)[nH]cnc32)[C@H](Br)[C@H]1OC(C)=O
HCID135976161

未命名化合物

PRODUCTS

生成物

3
结构：CC(=O)OC[C@@H]1C=C[C@H](n2cnc3c(N)ncnc32)O1
HCID11022122

[(2S,5R)-5-(6-aminopurin-9-yl)-2,5-dihydrofuran-2-yl]methyl acetate

C12H13N5O3

结构：CC(=O)OC[C@@H]1C=C[C@H](n2ccc(=O)[nH]c2=O)O1
HCID11791658

[(2S,5R)-5-(2,4-dioxopyrimidin-1-yl)-2,5-dihydrofuran-2-yl]methyl acetate

C11H12N2O5

结构：CC(=O)OC[C@@H]1C=C[C@H](n2cnc3c(O)ncnc32)O1
HCID178476336

未命名化合物

PROCEDURE

实验过程

The reaction conditions were identical to those in Table III but, in addition to 9-(2,5-di-O-acetyl-3-bromo-3-deoxy-β-D-xylofuranosyl)adenine, a mixture of 9-(2,5-di-O-acetyl-3-bromo-3-deoxy-β-D-xylofuranosyl)hypoxanthine and 9-(3,5-di-O-acetyl-2-bromo-2-deoxy-β-D-xylofuranosyl)hypoxanthine, and 3',5'-O-diacetyl-2'-bromo-2-deoxyuridine were used as substrates to give 5'-O-acetyl-2',3'-didehydro-2',3'-dideoxyadenosine, 5'-O-acetyl-2',3'-didehydro-2',3'-dideoxyinosine and 5'-O-acetyl-2',3'-didehydro-2',3'-dideoxyuridine.

WORKUP

后处理

  1. customThe reaction conditions