Stearyl Alcohol → HCID 19812763, compound

HRID 1031056Notes

Reaction equation

HRID 1031056 reaction equation
F[C:2]1[CH:19]=[CH:18][C:17]2[C:16](=[O:20])[C:15]3[C:6](=[CH:7][C:8]4[C:13]([CH:14]=3)=[CH:12][CH:11]=[CH:10][CH:9]=4)[C:5](=[O:21])[C:4]=2[CH:3]=1.[CH2:22]([OH:40])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39]>>[CH2:22]([O:40][C:2]1[CH:19]=[CH:18][C:17]2[C:16](=[O:20])[C:15]3[C:6](=[CH:7][C:8]4[C:13]([CH:14]=3)=[CH:12][CH:11]=[CH:10][CH:9]=4)[C:5](=[O:21])[C:4]=2[CH:3]=1)[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39]

Participants

3

Reactant 2

HCID 8221Stearyl AlcoholHCID 200898282-Fluorotetracene-5,12-dione

Product 1

HCID 19812763HCID 19812763, compound

Procedure

The procedure is analogous to Example 1, and 2-fluorotetracene-5,12-dione is reacted with 1-octadecanol, the 2-n-octadecyloxytetracene-5,12-dione obtained is converted into the corresponding diacetate by reductive acetylation, and the latter is reacted with sulfur in the presence of p-toluenesulfonic acid to form 2-n-octadecyloxytetracene-5,6,11,12-tetrathiotetracene. The individual reaction products have the following characteristic data:

Sources & evidence

ORD record
ord-4173c3b08a2e485ba672369b6b4a78d3
Source dataset
uspto-grants-1992_04
Patent number
US05108841

Reaction notes

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