Chlorine → HCID 19779379, compound

HRID 1031122Notes

Reaction equation

HRID 1031122 reaction equation
[Cl:1]Cl.[NH2:3][C:4]1[CH:9]=[CH:8][C:7]([C:10]([F:13])([F:12])[F:11])=[CH:6][C:5]=1[C:14]#[N:15]>>[NH2:3][C:4]1[C:5]([C:14]#[N:15])=[CH:6][C:7]([C:10]([F:11])([F:12])[F:13])=[CH:8][C:9]=1[Cl:1]

Participants

3

Reactant 2

HCID 24526ChlorineHCID 126273614-Amino-3-cyanobenzotrifluoride

Product 1

HCID 19779379HCID 19779379, compound

Procedure

Chlorine gas was passed through a stirred solution of 4-amino-3-cyano-trifluoromethylbenzene (5g) in carbon tetachloride (75ml) until the absence of starting material was confirmed by gas liquid chromatography. Flow of the gas was then stopped and evaporation of the solvent under reduced pressure gave 4-amino-3-chloro-5-cyanotrifluoromethylbenzene as an orange solid (5.5g).

Workup

  1. customevaporation of the solvent under reduced pressure

Sources & evidence

ORD record
ord-d265ec7e3dfd4c748a2cdbe152d4f7f0
Source dataset
uspto-grants-1992_04
Patent number
US05109004

Reaction notes

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