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HRID1031429

反应详情

EQUATION

反应方程式

HRID 1031429 的结构方程式

REACTANTS

反应物

1
结构：CC1CC(=O)NN=C1c1ccc(N)c([N+](=O)[O-])c1
HCID3111187

6-(4-Amino-3-nitrophenyl)-5-methyl-4,5-dihydropyridazin-3(2H)-one

C11H12N4O3

PRODUCTS

生成物

1
结构：CC1CC(=O)NN=C1c1ccc(N)c(N)c1
HCID3441052

6-(3,4-Diaminophenyl)-5-methyl-4,5-dihydropyridazin-3(2H)-one

C11H14N4O

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Pd]
催化剂HCID23938

Palladium

Pd

结构：CO
溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

100 g of 6-(4-amino-3-nitrophenyl)-5-methyl-2,3,4,5-tetrahydropyridazin-3-one are dissolved in 2 1 of methanol and hydrogenated over 20 g of 5% palladium-on-charcoal at 20° and 1 bar until absorption ceases. Filtration and evaporation give 6-(3,4-diaminophenyl)-5-methyl-2,3,4,5-tetrahydropyridazin-3-one, m.p. 195°-196°.

WORKUP

后处理

  1. custom1 bar until absorption ceases
  2. filtrationFiltration and evaporation