Sodium Hydroxide → HCID 22166242, compound

HRID 1031834Notes

Reaction equation

HRID 1031834 reaction equation
[C:1]1([C:7]([O:20]C(=O)C(F)(F)C(F)(F)C(F)(F)F)([CH3:19])[CH2:8][C:9]([F:18])([F:17])[C:10]([F:16])([F:15])[C:11]([F:14])([F:13])[F:12])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH-].[Na+]>ClC(F)(Cl)C(F)(F)Cl>[C:1]1([C:7]([OH:20])([CH3:19])[CH2:8][C:9]([F:17])([F:18])[C:10]([F:15])([F:16])[C:11]([F:13])([F:14])[F:12])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 13431582HCID 13431582, compound

Product 1

HCID 22166242HCID 22166242, compoundYield 98%

Reagents, catalysts & solvents 1

HCID 6428Cfc 113Solvent

Procedure

In 100 ml of 1,1,2-trichlorotrifluoroethane solution containing 5.00 g (0.01 mol) of 2-phenyl-2-heptafluorobutyryloxy-1-heptafluoropropyl propane ##STR19## 200 ml of an aqueous 10% sodium hydroxide solution added thereto was stirred. An organic layer was separated from the resultant mixture and was dried with magnesium sulfate. By analyzing the reaction product, i.e. the organic layer, by gas chromatography, IR, and NMR, the reaction was foundn to have produced 2-phenyl-2-hydroxy-1-heptafluoropropyl propane ##STR20## in a yield of 98%.

Workup

  1. additionadded
  2. customAn organic layer was separated from the resultant mixture
  3. dry with materialwas dried with magnesium sulfate

Sources & evidence

ORD record
ord-3e1cd57106e54a2282bdc3d3ee50e704
Source dataset
uspto-grants-1990_09
Patent number
US04956123

Reaction notes

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