HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bromopinacolone → HCID 178488979, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Bromopinacolone | HCID 21642 | — |
| Reactant | 1-(Benzylideneamino)-2-(p-methoxyphenyl)imidazole | HCID 54271470 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | HCID 178488979 | HCID 178488979 | — |
Reaction Steps
3.73 g of 1-bromo-3,3-dimethyl-2-butanone are added to a solution of 4.6 g of 1-(benzylideneamino)-2-(p-methoxyphenyl)imidazole in 250 ml of absolute acetonitrile. After stirring at 60° for 24 hours, the solution is evaporated and the residue is crystallized from ethanol/ether. There is obtained 1-(benzylideneamino)-2-(p-methoxyphenyl)-3-(pivaloylmethyl)imidazolium bromide of melting point 244°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04956470 |
| Source dataset | uspto-grants-1990_09 |
| ORD ID | ord-a02bdcbc67bc4239818a040b04e7bdb4 |
| Source note | uspto-grants-1990_09 |