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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1032279Generated: October 30, 2026

3-Furancarboxaldehyde, 5-(triethylsilyl)- → HCID 54253386, compound

https://huagongshe.com/reaction/1032279

Reaction equation

Participants

RoleNameHCIDCharge
Reactant3-Furancarboxaldehyde, 5-(triethylsilyl)-HCID 10878438—
ReactantHCID 22165582HCID 22165582—
ReactantButyllithiumHCID 178418339—
ProductHCID 54253386HCID 54253386—

Reaction Steps

5-Triethylsilyl-3-furaldehyde is reacted with diethyl 2-oxotridecylphosphonate and n-butyl lithium to give 5-triethylsilyl-3-(3-oxo-1-tetradecenyl)furan. Oxidizing using Rose Bengal and oxygen gives 4-(3-oxo-1-tetradecenyl)-5-hydroxy-2(5H)-furanone.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04957917
Source datasetuspto-grants-1990_09
ORD IDord-c751d9f23695493ab3ba700ebcc65a1a
Source noteuspto-grants-1990_09