HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Anhydride → HCID 22165551, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Anhydride | HCID 7918 | — |
| Reactant | Tetradecan-2-one | HCID 75364 | — |
| Reactant | Lithium diisopropylamide | HCID 2724682 | — |
| Reactant | 5-(Trimethylsilyl)furan-3-carbaldehyde | HCID 15663251 | — |
| Product | HCID 22165551 | HCID 22165551 | — |
Reaction Steps
5-Trimethylsilyl-3-furaldehyde is treated with lithium diisopropylamide and 2-tetradecanone, followed by acetic anhydride to give 3-(1-acetoxy-3-ketopentadecanyl)-5-trimethylsilylfuran. Oxidation by the method described in Example 1 gives 4-(1-acetoxy-3-ketopentadecanyl)-5-hydroxy-2(5H)-furanone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04957917 |
| Source dataset | uspto-grants-1990_09 |
| ORD ID | ord-45ebd511a339402bbc75a66efc380832 |
| Source note | uspto-grants-1990_09 |