Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → 1-Azido-3-acetoxyacetone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | Sodium Azide | HCID 33557 | — |
| 반응물 | 2-Propanone, 1-(acetyloxy)-3-chloro- | HCID 38413 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | 1-Azido-3-acetoxyacetone | HCID 14434780 | — |
반응 단계
1-Chloro-3-acetoxyacetone (15.05 g.) is dissolved in tetrahydrofuran (50 ml.) and water (25 ml.) is added. Sodium azide (8.7 g.) is added and the mixture is allowed to stir overnight at room temperature. The reaction mixture is diluted with ether (200 ml.) and the aqueous phase is separated. The organic phase is washed once with brine, then dried and evaporated to give 1-azido-3-acetoxyacetone.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04957912 |
| 출처 데이터셋 | uspto-grants-1990_09 |
| ORD ID | ord-961487a4299a4276a608f00d388e8d21 |
| 출처 메모 | uspto-grants-1990_09 |