HCID 11953989, compound → HCID 11953982, compound

HRID 1033725Notes

Reaction equation

[CH3:1][CH2:2][CH:3]([C@H:5]1[O:10][C@:9]2([O:15][C@@H:14]3[CH2:16][CH:17]=[C:18]([CH3:41])[C@@H:19]([OH:40])[C@@H:20]([CH3:39])[CH:21]=[CH:22][CH:23]=[C:24]4[CH2:25][O:26][C@@H:27]5[C@H:32]([OH:33])[C:31]([CH3:34])=[CH:30][C@@H:29]([C:35]([O:37][C@@H:12]([CH2:13]3)[CH2:11]2)=[O:36])[C@:28]45[OH:38])[CH:8]=[CH:7][C@@H:6]1[CH3:42])[CH3:4].CCC([C@H]1[O:52][C@]2(O[C@@H]3CC=C(C)[C@@H](O[C@@H]4O[C@@H](C)[C@H](O)[C@@H](OC)C4)[C@@H](C)C=CC=C4CO[C@@H]5[C@H](O)C(C)=C[C@@H](C(O[C@@H](C3)C2)=O)[C@]45O)C=C[C@@H]1C)C>>[CH3:1][CH2:2][CH:3]([C@H:5]1[O:10][C@:9]2([O:15][C@@H:14]3[CH2:16][CH:17]=[C:18]([CH3:41])[C@@H:19]([OH:40])[C@@H:20]([CH3:39])[CH:21]=[CH:22][CH:23]=[C:24]4[CH2:25][O:26][C@@H:27]5[C@H:32]([OH:33])[C:31]([CH3:34])=[CH:30][C@@H:29]([C:35]([O:37][C@@H:12]([CH2:13]3)[CH2:11]2)=[O:36])[C@:28]45[OH:38])[CH2:8][C@H:7]([OH:52])[C@@H:6]1[CH3:42])[CH3:4]

Participants

Reactant 2

HCID 11953989HCID 11953989, compound

HCID 11953991HCID 11953991, compound

Product 1

HCID 11953982HCID 11953982, compound

Procedure

13β-14a-hydroxy, avermectin B1a aglycone→13β-14a-hydroxy, avermectin B1a monosaccharide

Sources & evidence

ORD record: ord-a3a06259735a438582bdb3033d9c8c83
Source dataset: uspto-grants-1994_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05312753

Reaction notes

Loading…