HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triacetoxyperiodinane → Benzyl 9-oxo-3-azaspiro[5.5]undecane-3-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triacetoxyperiodinane | HCID 159087 | — |
| Reactant | HCID 67126666 | HCID 67126666 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | Benzyl 9-oxo-3-azaspiro[5.5]undecane-3-carboxylate | HCID 59803011 | — |
Reaction Steps
To a solution of EXAMPLE 265C (8.0 g) in dichloromethane (200 mL) was added Dess-Martin Periodinane (11.2 g). The mixture was stirred overnight. The mixture was diluted with ethyl acetate (400 mL) and washed with 2N aqueous NaOH, water, and brine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08546399B2 |
| Source dataset | uspto-grants-2013_10 |
| ORD ID | ord-ce0adbc2e4994be0b5eb6a6f139b34be |
| Source note | uspto-grants-2013_10 |