反应详情

To a solution of 1,3-di(carbazol-9-yl)benzene (1.0 g, 2.45 mmol) in 2-chloro-2-methylpropane (10.0 ml) was added aluminum trichloride (0.32 g, 2.40 mmol) at room temperature under nitrogen atmosphere and stirring. After the addition of AlCl3, insoluble 1,3-di(carbazol-9-yl)benzene disappeared within minutes. The green solid appeared after 5 minutes of reacting at room temperature. The reaction was carried out at room temperature for another 10 minutes. TLC showed that the reaction was finished. After which, water (20.0 ml) was added and the green solid became white. The solid product was collected with filtration and washed with methanol. The product was purified by recrystallization from acetone/THF/methanol to yield a white solid in the amount of 1.23 g (79.4%).

1. waitdisappeared within minutes
2. customof reacting at room temperature
3. waitThe reaction was carried out at room temperature for another 10 minutes
4. filtrationThe solid product was collected with filtration
5. washwashed with methanol
6. customThe product was purified by recrystallization from acetone/THF/methanol
7. customto yield a white solid in the amount of 1.23 g (79.4%)