HuagongsheHuagongshe Chemistry Print Report · For research reference only
tert-Butanol → Benzenepropanoic acid, 1,1-dimethylethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | tert-Butanol | HCID 6386 | — |
| Reactant | Methyl 3-phenylpropionate | HCID 7643 | — |
| Reactant | Diisopropyl Ether | HCID 7914 | — |
| Catalyst | Zinc | HCID 23994 | — |
| Product | Benzenepropanoic acid, 1,1-dimethylethyl ester | HCID 10878309 | — |
Reaction Steps
Under a nitrogen atmosphere, a mixture of methyl 3-phenylpropionate (3.0 mmol), t-butanol (3.6 mmol), a zinc cluster Zn4O (OCOF3)6 (0.0375 mmol), and diisopropyl ether (5.0 ml) was refluxed for 18 hours. As a result, t-butyl 3-phenylpropionate was obtained quantitatively.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08552204B2 |
| Source dataset | uspto-grants-2013_10 |
| ORD ID | ord-4f79f905e2b344a187fc239d2ce94c0e |
| Source note | uspto-grants-2013_10 |