HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-(3-(Benzyloxy)-4-chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane → Methyl 3''-(benzyloxy)-4''-chloro-2,6-dimethoxy-1,1':2',1''-terphenyl-4'-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-(3-(Benzyloxy)-4-chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | HCID 59846881 | — |
| Reactant | Methyl 2-bromo-2',6'-dimethoxybiphenyl-4-carboxylate | HCID 66721235 | — |
| Product | Methyl 3''-(benzyloxy)-4''-chloro-2,6-dimethoxy-1,1':2',1''-terphenyl-4'-carboxylate | HCID 66721104 | 45.1% |
Reaction Steps
According to the method described in example 10.2, starting from 2.79 g (7.94 mmol) of methyl 2-bromo-2′,6′-dimethoxybiphenyl-4-carboxylate and 3.28 g (9.53 mmol) of 2-[3-(benzyloxy)-4-chlorophenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, we obtain 1.75 g of methyl 3″-(benzyloxy)-4″-chloro-2,6-dimethoxy-1,1′:2′,1″-terphenyl-4′-carboxylate in the form of oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08552201B2 |
| Source dataset | uspto-grants-2013_10 |
| ORD ID | ord-d3054f920e3c405296bb968fa095477e |
| Source note | uspto-grants-2013_10 |