1,3-Difluoro-2-nitrobenzene → 305811-06-7

HRID 1041289Notes

Reaction equation

[F:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4](F)[C:3]=1[N+:9]([O-:11])=[O:10].[CH3:12][S-:13].[Na+]>>[F:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([S:13][CH3:12])[C:3]=1[N+:9]([O-:11])=[O:10]

Participants

Reactant 2

HCID 879221,3-Difluoro-2-nitrobenzene

HCID 4378561Sodium methanethiolate

Product 1

HCID 11052367305811-06-7

Procedure

1-Fluoro-3-methylsulfanyl-2-nitro-benzene was prepared from 1,3-difluoronitrobenzene and sodium methyl mercaptide in an analogous manner to Example 1251a. (1.513 g, 26%).

Sources & evidence

ORD record: ord-f8a8d731d9e547e6b5f078db8d35e99a
Source dataset: uspto-grants-2013_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08552186B2

Reaction notes

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