Ethanol → HCID 178524967, compound

HRID 1043986Notes

Reaction equation

HRID 1043986 reaction equation
[OH-].[K+:2].O.[NH:4]1[C:8]([C:9]([O:11]CC)=[O:10])=[N:7][N:6]=[N:5]1.CCO>>[NH:4]1[C:8]([C:9]([O-:11])=[O:10])=[N:7][N:6]=[N:5]1.[K+:2].[K+:2].[NH:4]1[C:8]([C:9]([O-:11])=[O:10])=[N:7][N:6]=[N:5]1

Participants

5

Reactant 4

HCID 702EthanolHCID 962WaterHCID 14797Potassium HydroxideHCID 178470518HCID 178470518, compound

Product 1

HCID 178524967HCID 178524967, compoundYield 128%

Procedure

A solution of potassium hydroxide (1.3 g, 23.2 mmol) in water (4.2 mL, 230 mmol) was added to a solution of ethyl tetrazole-5-carboxylate (1.1 g, 7.7 mmol) in EtOH (24 mL, 410 mmol). A solid product formed immediately and was collected and washed with cold EtOH to yield the title compound (1.5 g).

Workup

  1. customA solid product formed immediately
  2. customwas collected
  3. washwashed with cold EtOH

Sources & evidence

ORD record
ord-8491176821cd41d1acc7408f2b954cc6
Source dataset
uspto-grants-2013_10
Patent number
US08563512B2

Reaction notes

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