Titanium Tetrachloride → HCID 178460663, compound

HRID 1045123Notes

Reaction equation

HRID 1045123 reaction equation
[Ti](Cl)(Cl)(Cl)[Cl:2].[CH:6]([O:9][Ti:10](OC(C)C)([O:15][CH:16]([CH3:18])[CH3:17])[O:11][CH:12]([CH3:14])[CH3:13])([CH3:8])[CH3:7]>ClCCl>[Cl:2][Ti:10]([O:15][CH:16]([CH3:18])[CH3:17])([O:11][CH:12]([CH3:14])[CH3:13])[O:9][CH:6]([CH3:8])[CH3:7]

Participants

4

Reactant 2

HCID 24193Titanium TetrachlorideHCID 178460666HCID 178460666, compound

Product 1

HCID 178460663HCID 178460663, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent3×

Procedure

0.38 g (2.0 mmol) of titanium tetrachloride and 2 mL of anhydrous dichloromethane were weighed in a test tube equipped with a lid, and 1.7 g (6.0 mmol) of tetra-iso-propoxy titanium was added dropwise thereto while stirring. After stirring at room temperature for 60 minutes, the reaction solution was transferred to a 10-mL volumetric flask, and anhydrous dichloromethane was added thereto for diluting to 10 mL, whereby a uniform, colorless and transparent dichloromethane solution (0.80 mol/L) of chloro-tri-iso-propoxy titanium was obtained.

Workup

  1. additionwas added dropwise
  2. stirringAfter stirring at room temperature for 60 minutes
  3. customthe reaction solution was transferred to a 10-mL volumetric flask
  4. additionfor diluting to 10 mL, whereby a uniform

Sources & evidence

ORD record
ord-5d78449ec947429a955efbbf2e0516d0
Source dataset
uspto-grants-2013_10
Patent number
US08563786B2

Reaction notes

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