Potassium 1,1,2,2-tetrafluoroethanesulfonate → HCID 178444701, compound

HRID 1045254Notes

Reaction equation

HRID 1045254 reaction equation
[Cl-].[CH2:2]([N+:8]1[CH:12]=[CH:11][N:10]([CH3:13])[CH:9]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[F:14][C:15]([F:23])([S:19]([O-:22])(=[O:21])=[O:20])[CH:16]([F:18])[F:17].[K+].[Cl-].C([N+]1C=CN(C)C=1)CCCCC.CC(C)=O>CC(C)=O>[F:14][C:15]([F:23])([S:19]([O-:22])(=[O:21])=[O:20])[CH:16]([F:18])[F:17].[CH2:2]([N+:8]1[CH:12]=[CH:11][N:10]([CH3:13])[CH:9]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]

Participants

5

Reactant 3

HCID 58905542Potassium 1,1,2,2-tetrafluoroethanesulfonateHCID 178444699HCID 178444699, compoundHCID 178459076HCID 178459076, compound

Product 1

HCID 178444701HCID 178444701, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent2×

Procedure

1-Hexyl-3-methylimidazolium chloride (10 g, 0.0493 moles) was mixed with reagent-grade acetone (100 ml) in a large round-bottomed flask and stirred vigorously under a nitrogen blanket. Potassium 1,1,2,2-tetrafluoroethane sulfonate (TFES-K, 10 g, 0.0455 moles) was added to reagent grade acetone (100 ml) in a separate round-bottomed flask, and this solution was carefully added to the 1-hexyl-3-methylimidazolium chloride/acetone mixture. The mixture was left to stir overnight. The reaction mixture was then filtered using a large frit glass funnel to remove the white KCl precipitate formed, and the filtrate was placed on a rotary evaporator for 4 hours to remove the acetone.

Workup

  1. waitThe mixture was left
  2. stirringto stir overnight
  3. filtrationThe reaction mixture was then filtered
  4. customto remove the white KCl precipitate
  5. customformed
  6. customthe filtrate was placed on a rotary evaporator for 4 hours
  7. customto remove the acetone

Sources & evidence

ORD record
ord-202e6e0d56ea4a4f98fe7086a9d9dc9f
Source dataset
uspto-grants-2013_10
Patent number
US08568608B2

Reaction notes

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