Benzene, 1-bromo-3-iodo- → 3-(1-Naphthyl)-1-bromobenzene

HRID 1045286Notes

Reaction equation

HRID 1045286 reaction equation
[Br:1][C:2]1[CH:3]=[C:4](I)[CH:5]=[CH:6][CH:7]=1.[C:9]1(B(O)O)[C:18]2[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=2)[CH:12]=[CH:11][CH:10]=1>>[Br:1][C:2]1[CH:3]=[C:4]([C:17]2[C:18]3[C:13](=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:14]=[CH:15][CH:16]=2)[CH:5]=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 11561Benzene, 1-bromo-3-iodo-HCID 2545321-Naphthaleneboronic acid

Product 1

HCID 221380473-(1-Naphthyl)-1-bromobenzene

Procedure

1-(3-Bromophenyl)naphthalene was synthesized by the same method, except that in Synthetic Example 1, 3-bromoiodobenzene was used in place of 4-bromoiodobenzene and that 1-naphthaleneboronic acid was used in place of 2-naphthaleneboronic acid.

Sources & evidence

ORD record
ord-2399a818b1db476e94aaa3230a39f1b7
Source dataset
uspto-grants-2013_10
Patent number
US08568902B2

Reaction notes

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