HuagongsheHuagongshe Chemistry Print Report · For research reference only
tert-butyl N-(3-aminophenyl)carbamate → 5-(3-Aminophenyl)-1H-naphtho[1,2-b][1,4]diazepine-2,4(3H,5H)-dione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | tert-butyl N-(3-aminophenyl)carbamate | HCID 12877220 | — |
| Reactant | 1-Nitronaphthalen-2-yl triflate | HCID 14765273 | — |
| Reactant | HCID 117699184 | HCID 117699184 | — |
| Reactant | HCID 117699239 | HCID 117699239 | — |
| Product | 5-(3-Aminophenyl)-1H-naphtho[1,2-b][1,4]diazepine-2,4(3H,5H)-dione | HCID 117699192 | 17% |
Reaction Steps
By using 1-nitro-2-naphthyl trifluoromethanesulfonate (5.94 g, 18.5 mmol), and tert-butyl(3-aminophenyl)carbamate, the title compound (1.02 g, yield 17%) was obtained as brown crystals in the same manner as that of Example 1, (1), (2) and (3).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09382236B2 |
| Source dataset | uspto-grants-2016_07 |
| ORD ID | ord-2aed8a42787944fe9afd600a1a77c6c3 |
| Source note | uspto-grants-2016_07 |