HCID 21723401, compound → HCID 21723398, compound

HRID 1050288Notes

Reaction equation

HRID 1050288 reaction equation
[N:1]([C@@H:4]1[CH2:9][C@H:8]2[C@H:10]3[C@H:19]([CH2:20][CH2:21][C@:6]2([CH3:7])[C@H:5]1[OH:24])[C:18]1[CH:17]=[CH:16][C:15]([O:22][CH3:23])=[CH:14][C:13]=1[CH2:12][CH2:11]3)=[N+:2]=[N-:3]>CC(C)=O>[N:1]([C@@H:4]1[CH2:9][C@H:8]2[C@H:10]3[C@H:19]([CH2:20][CH2:21][C@:6]2([CH3:7])[C@@H:5]1[OH:24])[C:18]1[CH:17]=[CH:16][C:15]([O:22][CH3:23])=[CH:14][C:13]=1[CH2:12][CH2:11]3)=[N+:2]=[N-:3]

Participants

3

Reactant 1

HCID 21723401HCID 21723401, compound

Product 1

HCID 21723398HCID 21723398, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

Using 150 ml acetone, finally also 0.4 g 16α-azido-3-methoxy-estra-1,3,5(10)-triene-17β-ol (13%) is eluted.

Workup

  1. washis eluted

Sources & evidence

ORD record
ord-119e2a9862b846f1b7995194b2ecc96f
Source dataset
uspto-grants-2016_07
Patent number
US09382288B2

Reaction notes

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