HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethyl acetylenedicarboxylate → HCID 11033155, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethyl acetylenedicarboxylate | HCID 12980 | — |
| Reactant | 5-phenyl-1,3,4-oxathiazol-2-one | HCID 853170 | — |
| Solvent | Chlorobenzene | HCID 7964 | — |
| Product | HCID 11033155 | HCID 11033155 | 59.5% |
Reaction Steps
A solution of 5-phenyl-[1,3,4]oxathiazol-2-one (30.33 mmol) and dimethylacetylenedicarboxylate (60.67 mmol) in chlorobenzene (17.8 mL) was refluxed with stirring for 6 h before it was concentrated in vacuo. The residue was crystallized from cold MeOH to give the title compound (5.0 g) as a slightly yellow solid: MS (m/z) 278.1 (M+1).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09387200B2 |
| Source dataset | uspto-grants-2016_07 |
| ORD ID | ord-8d3eb03966d143339f3bb04e04b4ebf6 |
| Source note | uspto-grants-2016_07 |