HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl 3-chloro-4-isopropoxybenzoate → 3-Chloro-4-(propan-2-yloxy)benzoic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl 3-chloro-4-isopropoxybenzoate | HCID 22597811 | — |
| Reactant | 3-Cyano-5-isopropoxybenzoic acid | HCID 67196214 | — |
| Product | 3-Chloro-4-(propan-2-yloxy)benzoic acid | HCID 22597728 | — |
Reaction Steps
Prepared from methyl 3-chloro-4-isopropoxybenzoate according to the procedure for 3-cyano-5-isopropoxybenzoic acid. LCMS-ESI (m/z) calculated for C10H11CLO3: 214.7. found 215.0 [M+H]+, tR=3.22 min. 1H NMR (400 MHz, CDCl3) δ 12.94 (s, 1H), 7.98-7.74 (m, 2H), 7.26 (d, J=8.9 Hz, 1H), 4.80 (dt, J=12.1, 6.0 Hz, 1H), 1.33 (t, J=5.6 Hz, 6H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09388147B2 |
| Source dataset | uspto-grants-2016_07 |
| ORD ID | ord-ea877122345d480fa593605ef77fafa6 |
| Source note | uspto-grants-2016_07 |