HRID1051154

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID14261

N-decyl-1-decanamine

C20H43N

HCID16213275

3,7-Dibromophenothiazin-5-ium bromide

C12H6Br3NS

PRODUCTS

生成物

结构：CCCCCCCCCCN(CCCCCCCCCC)c1ccc2nc3ccc(N(CCCCCCCCCC)CCCCCCCCCC)cc3[s+]c2c1.[Br-]

HCID178443398

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6212

Chloroform

CHCl3

PROCEDURE

实验过程

To a solution of 1.7 g (5.72 mmol) of didecylamine in 20 mL of CHCl3 was added 0.63 g (1.43 mmol) of 22. The reaction mixture was stirred at room temperature for 2 h under argon and concentrated under diminished pressure to give 3,7-bis(didecylamino)phenothiazin-5-ium bromide (CPD-14): mass spectrum (MALDI-TOF), m/z 788.69 (M+).

WORKUP

后处理

concentrationconcentrated under diminished pressure

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-908db483963e4e948e5a0e4b787928c1
来源数据集: uspto-grants-2016_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US09388163B2
来源说明: uspto-grants-2016_07

反应 SMILES

[CH2:1]([NH:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[Br-].[Br:23][C:24]1[CH:25]=[CH:26][C:27]2[C:36]([CH:37]=1)=[S+:35][C:34]1[C:29](=[CH:30][CH:31]=[C:32](Br)[CH:33]=1)[N:28]=2>C(Cl)(Cl)Cl>[Br-:23].[CH2:12]([N:11]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[C:24]1[CH:25]=[CH:26][C:27]2[C:36]([CH:37]=1)=[S+:35][C:34]1[C:29](=[CH:30][CH:31]=[C:32]([N:11]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH:33]=1)[N:28]=2)[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]