Dichloromethane → toluene-4-sulfonic acid 5-acetyl-4-cyclopentyl-1H-pyrazol-3-yl ester

HRID 105345Notes

Reaction equation

HRID 105345 reaction equation
[CH:1]1([c:6]2[c:7]([O:14][S:15](=[O:16])(=[O:17])[c:18]3[cH:19][cH:20][c:21]([CH3:24])[cH:22][cH:23]3)[n:8][nH:9][c:10]2[CH:11]([CH3:12])[OH:13])[CH2:2][CH2:3][CH2:4][CH2:5]1.[Cl:46][CH2:47][Cl:48].[Cr:25]([O:26][Cr:27]([O-:28])(=[O:29])=[O:30])([O-:31])(=[O:32])=[O:33].[nH+:34]1[cH:35][cH:36][cH:37][cH:38][cH:39]1.[nH+:40]1[cH:41][cH:42][cH:43][cH:44][cH:45]1>>[CH:1]1([c:6]2[c:7]([O:14][S:15](=[O:16])(=[O:17])[c:18]3[cH:19][cH:20][c:21]([CH3:24])[cH:22][cH:23]3)[n:8][nH:9][c:10]2[C:11]([CH3:12])=[O:13])[CH2:2][CH2:3][CH2:4][CH2:5]1

Participants

5

Reactant 4

HCID 6344DichloromethaneHCID 24503Dichromate ionHCID 4989215Pyridinium2×HCID 86587507toluene-4-sulfonic acid 4-cyclopentyl-5-(1-hydroxyethyl)-1H-pyrazol-3-yl ester

Product 1

HCID 86587506toluene-4-sulfonic acid 5-acetyl-4-cyclopentyl-1H-pyrazol-3-yl ester

Sources & evidence

ORD record
ord-bb5736607a994676b23f07541470e09b
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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